Capturing temporal variability for estimates of annual hydrochemical export from a first‐order agricultural catchment in southern Ontario,Canada     

M. L. Macrae  M. C. English  S. L. Schiff  M. Stone 《水文研究》2007,21(13):1651-1663

This 2‐year study (2000, 2001) reports annual nutrient (phosphorus, nitrate) export from a first‐order agricultural watershed in southern Ontario based on an intensive monitoring programme. The importance of storm and melt events in annual export estimates is demonstrated and the temporal variability in nutrient loading during events is related to processes occurring within the catchment. The feasibility of predicting event‐related nutrient export from hydrometric data is explored. The importance of sampling frequency throughout events is also shown. Export of total phosphorus (TP), soluble reactive phosphorus (SRP) and nitrate ( ) for 2000 and 2001 averaged 0·35 kg ha^?1 year^?1, 0·09 kg ha^?1 year^?1, and 35 kg ha^?1 year^?1 (as N) respectively. Approximately 75% of annual TP export, 80% of annual SRP export and 70% of annual export occurred during 28 events per year. A small number of large‐magnitude events (>34 mm) accounted for 18–42% of annual TP export, 0–61% of annual SRP export and 13–33% of annual NO export. Our results show that temporal variability in nutrient export is largely governed by discharge in this basin, and export can be predicted from discharge. SRP and TP export can also be predicted from discharge, but only for events that are not large in magnitude. The sampling interval throughout events is important in obtaining precise estimates of nutrient export, as infrequent sampling intervals may over‐ or under‐estimate nutrient export by ± 45% per event for P. This study improves our understanding of and P export patterns and our ability to predict or model them by relating temporal variability in event nutrient export to discharge and processes occurring within the basin, and also by exploring the significance of sampling interval in the context of the importance of individual events, season and temporal variability during events. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene     

Jillian Baker  Janet Arey  Roger Atkinson 《Journal of Atmospheric Chemistry》2004,48(3):241-260

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.  相似文献   

Assessment of Nitrate—Nitrogen Distribution in Kansas Groundwater, 1990–1998     

Townsend  M. A.  Young  D. P. 《Natural Resources Research》2000,9(2):125-134

Nitrate-nitrogen (nitrate-N) in groundwater is a potential problem in many parts of Kansas.From 1990 to 1998, 747 water samples were collected from domestic, irrigation, monitoring,and public water supply wells primarily from the western two-thirds of the state, and analyzedfor nitrate-N by the Kansas Geological Survey. Nitrate-N concentrations of the 747 samplesanalyzed range from 29% with less than or equal to 3 mg/L, 51% between 3 and 10 mg/L,and 20% greater than or equal to 10 mg/L. Factors that show a statistically significantrelationship with the occurrence of nitrate-N in Kansas groundwater in this assessment includegeographic area of the state, depth of well, and age of well. Nitrate-N levels of wells screenedin the High Plains aquifer in south-central Kansas showed a statistically higher concentrationthan samples collected from the High Plains aquifer in the western portion of the state.Comparison of nitrate-N with depth of well indicated that shallower wells throughout the stategenerally have higher nitrate-N values than deeper wells. Irrigation wells older than 1975showed statistically higher nitrate-N concentration than wells installed during and since 1975,possibly related to changes in well-construction practices and regulations that occurred in 1975.  相似文献   

Preliminary study on the dissolved and colloidal organic carbon in the Zhujiang River estuary   总被引：3，自引：0，他引：3  

戴民汉  洪华生  张祖麟 《中国海洋湖沼学报》2000,18(3):265-273

ＩＮＴＲＯＤＵＣＴＩＯＮＥｓｔｕａｒｉｅｓｃｏｍｐｒｉｓｅａｍａｊｏｒｂｉｏｇｅｏｃｈｅｍｉｃａｌｉｎｔｅｒｆａｃｅｃｏｎｎｅｃｔｉｎｇｔｈｅｌａｎｄａｎｄｔｈｅｓｅａ (Ｍａｎ ｔｏｕｒａ,1 987) .Ｔｈｅｂｅｈａｖｉｏｒａｎｄｆａｔｅｏｆａｐａｒｔｉｃｕｌａｒｒｉｖｅｒ ｂｏｒｎｅｓｕｂｓｔａｎｃｅｉｎｔｒｏｄｕｃｅｄｉｎｔｏａｎｅｓｔｕａｒｙｉｓｄｅｔｅｒｍｉｎｅｄｔｏａｌａｒｇｅｅｘｔｅｎｔｂｙｔｈｅｂｉｏｇｅｏｃｈｅｍｉｃａｌｐｒｏｐｅｒｔｉｅｓｏｆｔｈｅｓｕｂｓｔａｎｃｅａｓｗｅｌｌａｓｐ…  相似文献   

The impact of agricultural land use on stream chemistry and inputs to an inland reservoir: case of the Sauce Grande River,Argentina     

《水文科学杂志》2013,58(4):834-843

Abstract

Water quality in the Paso Piedras Reservoir has deteriorated, primarily due to periodic blue-green algal blooms, making it temporarily unfit for human consumption. This phenomenon results from the eutrophication of waters of the watershed, and nutrients are considered to be the primary contributors to degradation of freshwater quality. In order to reduce the levels of nitrogen and, most of all, phosphorus, entering the Paso Piedras Reservoir, it is necessary to understand the incidence of diffuse transfers of nutrients from agricultural soils. The nitrogen composition, soluble reactive phosphorus (SRP) and other physico-chemical parameters of the water were analysed in various different parts of the watershed in order to characterize water input to the reservoir from areas with different anthropogenic activity. The upper Sauce Grande basin was divided into three areas with different edaphic characteristics. The physico-chemical parameters measured in sampling surveys included: SRP, ammonium and nitrate, pH, conductivity, turbidity, and total solids. The results showed that the water of the Sauce Grande (areas 1 and 2) was not strongly contaminated, but in El Divisorio (Area 3, which is a sub-watershed whose stream flows directly into the Paso Piedras Reservoir), the levels of conductivity, total suspended sediments and SRP were so high that its contribution to the reservoir accounts for nearly 50% of the total SRP input. The main characteristics of El Divisorio watershed that make it a diffuse source of SRP were not only that its soils, under agricultural-livestock production, have significant slopes, so that water and wind erosion are faster, but also that human intervention had caused the destruction of aggregates. The results showed the influence of the soil characteristics, production systems and the micro-environment developed in the reservoir on the characteristics of waters flowing out of the reservoir. The two villages located in Area 2 had no significant influence on the concentration of nitrogen compounds and SRP found downstream.  相似文献   

新疆库米什盆地硝酸盐类矿床成矿离子迁移规律及成矿模型          下载免费PDF全文

李长忠  程怀德  宋建国  马学海  海擎宇  蒋天明 《地球科学》2022,47(1):82-93

为了深入认识库米什盆地硝酸盐矿床成矿离子的空间分布特征、表层沉积物中硝酸盐含量较高的原因,以盆地硝酸盐矿床为研究对象,开展研究区内各类补给水样和沉积物样可溶性盐类物质化学组成的定量分析研究;结合野外地质踏勘工作,探讨研究区硝酸盐矿床成矿离子的迁移规律,初步建立盆地硝酸盐矿床沉积成矿作用模型.结果表明,K+、Na+、NO...  相似文献   

铵锌镉还原法测试硝酸盐氮、氧同位素方法研究          下载免费PDF全文

尹希杰  杨海丽  郭浩然  陈淳青  崔坤磊 《应用海洋学学报》2021,40(4):721-727

本研究利用铵锌镉还原法将海水、湖水和自来水水体中硝酸盐转化为N₂O气体测试氮、氧同位素, 结果表明当反应体系的pH值在6～8之间, NO₃^-还原为NO₂^-的转化率大于95%, NO₂^-还原为N₂O的转化率大于99%。配置5种丰度的硝酸盐氮、氧同位素标样, 将实验结果与理论值绘制校准曲线, 氮同位素校准曲线斜率为0.48, 相关性良好(R²=0.999 8), 5种丰度δ¹⁵N_N2O标准偏差在0.18‰～0.43‰之间(n=5);氧同位素校准曲线斜率为0.70, 相关性良好(R²=0.999 6), 5种丰度δ¹⁸O_N2O标准偏差在0.27‰～0.46‰之间(n=5)。铵锌镉还原法与镉柱还原法测定硝酸盐氮、氧同位素结果的精密度和准确度一致, 同时海水、湖水和自来水3种不同类型水样的硝酸盐氮、氧同位素测试数据满足实验要求, 而且在实验流程的简洁性和高效性方面更具优势。  相似文献   

细菌反硝化法测试硝酸盐氮、氧同位素的研究与应用          下载免费PDF全文

崔坤磊  尹希杰  李艳利  杨海丽  裴盛祥  苏静 《应用海洋学学报》2021,40(4):629-635

为了验证细菌反硝化法对水体中硝酸盐氮、氧同位素组成测定的适用性、重现性及准确性, 在不同时间(2019年7月28日、8月19日、8月26日)利用反硝化细菌分别将海水、湖水和自来水样品中的硝酸盐转化为氧化亚氮（N₂O）, 并进行氮、氧同位素测定。结果表明, 不同时间段3个批次实验的硝酸盐氮同位素校准曲线斜率都接近理论值1, 相关性系数均高于0.999, 说明反硝化细菌在将样品中的硝酸盐全部还原为N₂O的过程中氮同位素分馏效应很小; 同一样品3个批次测定的硝酸盐的氮同位素值基本相同, 表明细菌反硝化法对硝酸盐氮同位素的测定在长时间周期内具有很好的重现性和准确性。3个批次氧同位素校准曲线斜率稳定在0.61～0.63之间, 相关性系数均高于0.99, 单批次内海水、湖水和自来水3类样品中硝酸盐氧同位素比值的标准偏差范围在0.18‰～0.69‰之间, 表明经过氧同位素校准曲线的校正, 可以准确反映样品中硝酸盐氧同位素组成; 同一样品3个批次测定的氧同位素值差异较大, 其变化范围为1.33‰～16.38‰, 可能是由于样品储存过程中硝酸盐与水之间发生的氧同位素交换作用所致。  相似文献   

一种合成2,2-二甲基-4-戊烯酸的方法     

钱佐国  孙明昆  李东慧  邹忠英 《中国海洋大学学报(自然科学版)》1999,(2)

报道一种合成２,２－二甲基－４－戊烯酸的新方法。由异丁醛与烯丙醇缩合得到２,２－二甲基－４－戊烯醛,后者经氧化银选择氧化生成２,２－二甲基－４－戊烯酸。此法氧化产率（９６％）高于分子氧氧化法（６１％）和歧化法（４１％）。反应中析出的金属银能定量回收,循环使用。  相似文献   

商业平板式超滤膜包完整性检验：对海洋胶体生物地球化学研究的启示     

LIN Liangshi  CAI Yihu  SUN Xiuwu  CHEN Min 《海洋学报(英文版)》2014,33(9):109-116

The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information.  相似文献